Outermost means furthest from the centre. The outermost ring, the outermost islands, its outermost edge.
It is a superlative with no ordinary positive behind it, like innermost and uppermost — there is no out to compare from. The -most ending here is not the word most: it comes from an old superlative ending that was reshaped to look like it.
1adjectiveoutermostFurthest from the centre.
“Pluto was once thought to be the outermost planet of our solar system.”
outermost is a position.
Old English utemest is a double superlative. The -most ending was reshaped later to look like the word most.
Old English
ūtemest
Middle English
uttermost
English, today
outermost
Built from
From Middle English uttermost, uttirmest, uttermast, outemast, alteration (due to Middle English outre (“outer”)) of Old English ūtemest, ȳtemest (“outermost”), equivalent to outer + most. a doublet of uttermost.
Etymology from Wiktionary, CC BY-SA